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I have a Calphalon stockpot and have the same problem with the residue on it. It was not as much of an issue when I was living in Washington but here in Arizona it's constant. I've always assumed it was due to the terribly high mineral content of the water here(the water here is awful....bottled or a reverse osmosis system is a must). I can get it clean but it takes a bit of time and patience. Bar Keeper's Friend does a good job on it.
 
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